Template:Infobox boron
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boron (β-rhombohedral)[1] | ||||||||||||||||
Boron | ||||||||||||||||
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Pronunciation | /ˈbɔːrɒn/ | |||||||||||||||
Allotropes | α-, β-rhombohedral, β-tetragonal (and more) | |||||||||||||||
Appearance | black-brown | |||||||||||||||
Standard atomic weight Ar, std(B) | [10.806, 10.821] conventional: 10.81 | |||||||||||||||
Boron in the periodic table | ||||||||||||||||
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Atomic number (Z) | 5 | |||||||||||||||
Group | group 13 (boron group) | |||||||||||||||
Period | period 2 | |||||||||||||||
Block | p-block | |||||||||||||||
Element category | p-block | |||||||||||||||
Electron configuration | [He] 2s2 2p1 | |||||||||||||||
Electrons per shell | 2, 3 | |||||||||||||||
Physical properties | ||||||||||||||||
Phase at STP | solid | |||||||||||||||
Melting point | 2349 K (2076 °C, 3769 °F) | |||||||||||||||
Boiling point | 4200 K (3927 °C, 7101 °F) | |||||||||||||||
Density when liquid (at m.p.) | 2.08 g/cm3 | |||||||||||||||
Heat of fusion | 50.2 kJ/mol | |||||||||||||||
Heat of vaporization | 508 kJ/mol | |||||||||||||||
Molar heat capacity | 11.087 J/(mol·K) | |||||||||||||||
Vapor pressure
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Atomic properties | ||||||||||||||||
Oxidation states | −5, −1, 0,[2] +1, +2, +3[3][4] (a mildly acidic oxide) | |||||||||||||||
Electronegativity | Pauling scale: 2.04 | |||||||||||||||
Ionization energies |
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Atomic radius | empirical: 90 pm | |||||||||||||||
Covalent radius | 84±3 pm | |||||||||||||||
Van der Waals radius | 192 pm | |||||||||||||||
Spectral lines of boron | ||||||||||||||||
Other properties | ||||||||||||||||
Natural occurrence | primordial | |||||||||||||||
Crystal structure | rhombohedral | |||||||||||||||
Speed of sound thin rod | 16,200 m/s (at 20 °C) | |||||||||||||||
Thermal expansion | β form: 5–7 µm/(m·K) (at 25 °C)[5] | |||||||||||||||
Thermal conductivity | 27.4 W/(m·K) | |||||||||||||||
Electrical resistivity | ~106 Ω·m (at 20 °C) | |||||||||||||||
Magnetic ordering | diamagnetic[6] | |||||||||||||||
Magnetic susceptibility | −6.7·10−6 cm3/mol[6] | |||||||||||||||
Mohs hardness | ~9.5 | |||||||||||||||
CAS Number | 7440-42-8 | |||||||||||||||
History | ||||||||||||||||
Discovery | Joseph Louis Gay-Lussac and Louis Jacques Thénard[7] (30 June 1808) | |||||||||||||||
First isolation | Humphry Davy[8] (9 July 1808) | |||||||||||||||
Main isotopes of boron | ||||||||||||||||
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10B content is 19.1–20.3% in natural samples, with the remainder being 11B.[10] | ||||||||||||||||
B data m.p. cat
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in | calc from C | diff | report | ref | |
C | 2076 | — | — | ||
K | 2349 | 2349 | 0 | ||
F | 3769 | 3769 | 0 | ||
max precision | 0 | ||||
WD |
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input | C: 2076, K: 2349, F: 3769 | ||||
comment |
B data b.p. cat
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in | calc from C | diff | report | ref | |
C | 3927 | — | — | ||
K | 4200 | 4200 | 0 | ||
F | 7101 | 7101 | 0 | ||
max precision | 0 | ||||
WD |
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input | C: 3927, K: 4200, F: 7101 | ||||
comment |
Be ← |
→ C | |
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[ Data sets read by {{Infobox element}} | ]|
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Name and identifiers | |
Top image (caption, alt) | |
Pronunciation | |
Category (enwiki) | |
Standard atomic weight | |
most stable isotope | |
Natural occurrence | |
Phase at STP | |
Chemistry:Oxidation states | |
Spectral lines image | |
Physics:Electron configuration (cmt, ref) | |
Term symbol * (cmt, ref) | |
Wikidata * | |
* Not used in {{Infobox element}} (2019-02-03) See also {{Infobox element/symbol-to--navbox}} |
References
- ↑ Van Setten et al. 2007, pp. 2460–1
- ↑ Braunschweig, H.; Dewhurst, R. D.; Hammond, K.; Mies, J.; Radacki, K.; Vargas, A. (2012). "Ambient-Temperature Isolation of a Compound with a Boron-Boron Triple Bond". Science 336 (6087): 1420–2. doi:10.1126/science.1221138. PMID 22700924. Bibcode: 2012Sci...336.1420B.
- ↑ Zhang, K.Q.; Guo, B.; Braun, V.; Dulick, M.; Bernath, P.F. (1995). "Infrared Emission Spectroscopy of BF and AIF". J. Molecular Spectroscopy 170 (1): 82. doi:10.1006/jmsp.1995.1058. Bibcode: 1995JMoSp.170...82Z. http://bernath.uwaterloo.ca/media/125.pdf.
- ↑ Melanie Schroeder (in de). Eigenschaften von borreichen Boriden und Scandium-Aluminium-Oxid-Carbiden. p. 139. https://www.deutsche-digitale-bibliothek.de/binary/KKUKEQ5AXZBNJVU7NJCHZB4UXT2HAGJE/full/1.pdf.
- ↑ Holcombe Jr., C. E.; Smith, D. D.; Lorc, J. D.; Duerlesen, W. K.; Carpenter; D. A. (October 1973). "Physical-Chemical Properties of beta-Rhombohedral Boron". High Temp. Sci. 5 (5): 349–57.
- ↑ 6.0 6.1 Haynes, William M., ed (2016). CRC Handbook of Chemistry and Physics (97th ed.). CRC Press. p. 4.127. ISBN 9781498754293.
- ↑ Gay Lussac, J.L.; Thenard, L.J. (1808). "Sur la décomposition et la recomposition de l'acide boracique". Annales de chimie 68: 169–174. https://books.google.com/books?id=e6Aw616K5ysC&pg=PA169.
- ↑ Davy H (1809). "An account of some new analytical researches on the nature of certain bodies, particularly the alkalies, phosphorus, sulphur, carbonaceous matter, and the acids hitherto undecomposed: with some general observations on chemical theory". Philosophical Transactions of the Royal Society of London 99: 39–104. doi:10.1098/rstl.1809.0005. https://books.google.com/books?id=gpwEAAAAYAAJ&pg=PA140.
- ↑ 9.0 9.1 "Atomic Weights and Isotopic Compositions for All Elements". National Institute of Standards and Technology. http://physics.nist.gov/cgi-bin/Compositions/stand_alone.pl. Retrieved 2008-09-21.
- ↑ Szegedi, S.; Váradi, M.; Buczkó, Cs. M.; Várnagy, M.; Sztaricskai, T. (1990). "Determination of boron in glass by neutron transmission method". Journal of Radioanalytical and Nuclear Chemistry Letters 146 (3): 177. doi:10.1007/BF02165219.
Five of these are named references. They may be cited in the containing article as
- <ref name="v1" /> for the source Infrared Emission Spectroscopy of BF and AIF
- <ref name="magnet" /> for the source from Handbook of Chemistry and Physics
- <ref name="NISTic" /> for the source Atomic Weights and Isotopic Compositions for All Elements
- <ref name="Lussac" /> for the source by Gay-Lussac
- <ref name="Davy" /> for the source by Davy