Chemistry:Zirconium selenate

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Zirconium selenate
Selenate.png
Zr4+.svg
Selenate.png
Identifiers
3D model (JSmol)
Properties
Zr(SeO4)2
Density 3.806 g·cm−3 (monohydrate)[1]
3.36 g·cm−3 (tetrahydrate) [2]
Boiling point 580 °C (dec.)[3]
soluble (tetrahydrate)
Related compounds
Other anions
zirconium sulfate
Other cations
hafnium selenate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references
Tracking categories (test):

Zirconium selenate is an inorganic compound with the chemical formula Zr(SeO4)2. Its tetrahydrate can be obtained by the reaction of selenic acid and a saturated aqueous solution of zirconium oxychloride octahydrate (or zirconium hydroxide[2]). The tetrahydrate belongs to the orthorhombic crystal system and is isostructural with Zr(SO4)2·4H2O. It loses water when heated and becomes anhydrous at 220-230 °C.[3] It reacts with potassium fluoride to obtain K2Zr(SeO4)2F2·3H2O.[4]

References

  1. Cite error: Invalid <ref> tag; no text was provided for refs named Giester
  2. 2.0 2.1 M. A. Nabar, V. R. Ajgaonkar (1978-02-01). "Studies on selenates. III. Crystal chemical data for zirconium and cerium selenate tetrahydrates". Journal of Applied Crystallography 11 (1): 56–57. doi:10.1107/S0021889878012686. ISSN 0021-8898. Bibcode1978JApCr..11...56N. http://scripts.iucr.org/cgi-bin/paper?S0021889878012686. Retrieved 2020-11-28. 
  3. 3.0 3.1 Davidovich, R. L.; Medkov, M. A. Zirconium and hafnium diselenates. Koordinatsionnaya Khimiya, 1975. (1) 11: 1478-1480. ISSN 0132-344X.
  4. Davidovich, R. L.; Medkov, M. A. Selenatofluoride complex compounds of zirconium and hafnium. Koordinatsionnaya Khimiya, 1975. 1 (12): 1646-1653. ISSN 0132-344X.