Chemistry:Tetrakis(trimethylsilyloxy)silane

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Tetrakis(trimethylsilyloxy)silane
Tetrakistrimethylsilyloxysilane.jpg
Names
Preferred IUPAC name
Tetrakis(trimethylsilyl) silicate
Identifiers
3D model (JSmol)
Abbreviations TTMS
ChemSpider
EC Number
  • 222-613-4
UNII
Properties
C12H36O4Si5
Molar mass 384.841 g·mol−1
Appearance Colourless liquid
Density 0.87 g cm−3[1]
Melting point −60 °C (−76 °F; 213 K)
Boiling point 103–106 °C (217–223 °F; 376–379 K)
Vapor pressure 8.96 Pa (25°C)
1.389
Hazards
GHS pictograms GHS07: Harmful
GHS Signal word Warning
H315, H319, H335, H413
P261, P264, P271, P273, P280, P302+352, P304+340, P305+351+338, P312, P321, P332+313, P337+313, P362, P403+233, P405, P501
Flash point 80 °C (176 °F; 353 K)
Related compounds
Related compounds
Hexamethyldisiloxane

Octamethylcyclotetrasiloxane

Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Tetrakis(trimethylsilyloxy)silane (TTMS) is an organosilicon compound with the formula Si[OSi(CH3)3]4. This colourless liquid is used as a reagent in organic synthesis.[2]

Application

TTMS can be used for thin film coating with a nanostructured silicon dioxide prepared by plasma-enhanced chemical vapor deposition (PECVD) at atmospheric pressure.[3]

References

  1. "TETRAKIS(TRIMETHYLSILOXY)SILANE - 3555-47-3". http://www.chemicalbook.com/ChemicalProductProperty_EN_CB5119530.htm. 
  2. Fleming, I (2002). Science of Synthesis: Houben-Weyl Methods of Molecular Transformations. Stuttgart: Georg Thieme Verlag. pp. 1060. ISBN 3-13-112171-8. 
  3. Schäfer, J; Hnilica, J; Sperka, J; Quade, A; Kudrle, V; Foest, R; Vodak, J; Zajickova, L (2016). "Tetrakis(trimethylsilyloxy)silane for nanostructured SiO2-like films deposited by PECVD at atmospheric pressure". Surface & Coatings Technology 295 (295): 112–118. doi:10.1016/j.surfcoat.2015.09.047. https://is.muni.cz/repo/1317983. 

External links