Chemistry:Pentafluoroethyl iodide
From HandWiki
| |||
| Names | |||
|---|---|---|---|
| Preferred IUPAC name
Pentafluoro(iodo)ethane | |||
| Identifiers | |||
3D model (JSmol)
|
|||
| ChemSpider | |||
| EC Number |
| ||
PubChem CID
|
|||
| UNII | |||
| |||
| |||
| Properties | |||
| C2F5I | |||
| Molar mass | 245.918 g·mol−1 | ||
| Appearance | pungent colourless gas[1] | ||
| Density | 2.085 g·cm−3[1] | ||
| Melting point | −92[1] °C (−134 °F; 181 K) | ||
| Boiling point | 12–13[1] °C (54–55 °F; 285–286 K) | ||
| Hazards | |||
| GHS pictograms |  
| ||
| GHS Signal word | Warning | ||
| H280, H315, H319, H335, H336 | |||
| P261, P264, P271, P280, P302+352, P304+340, P305+351+338, P312, P321, P332+313, P337+313, P362, P403+233, P405, P410+403, P501 | |||
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |||
 verify (what is   ?)
| |||
| Infobox references | |||
Tracking categories (test):
Pentafluoroethyl iodide is a suggested component of a fire-extinguishing composition.[2] It is a very dense gas.
Production
Pentafluoroethyl iodide can be produced by electrochemical fluorination of 1,1,2,2-tetrafluoro-1,2-diiodoethane.[3]
- [math]\ce{ 2 C2F4I2 + 2 HF -> C2F5I + I2 + H2 }[/math]
It can also be produced by react tetrafluoroethylene, iodine and iodine pentafluoride.[4]
- [math]\ce{ 5 C2F4 + 2 I2 + IF5 -> 5 C2F5I }[/math]
Properties
Pentafluoroethyl iodide is a pungent colourless gas[1] and an anesthetic.[5][6]
Uses
Pentafluoroethyl iodide is an intermediate of preparing other compounds.[7][8][9]
References
- ↑ 1.0 1.1 1.2 1.3 1.4 Record of Pentafluoriodethan in the GESTIS Substance Database of the Institute for Occupational Safety and Health, accessed on 2019-01-07.
- ↑ US patent application 20010048094
- ↑ Bernd Baasner (2014). Houben-Weyl Methods of Organic Chemistry Vol. E 10a, 4th Edition Supplement Organo-Fluorine Compounds - Fluorinating Agents and Their Application in Organic Synthesis. Georg Thieme Verlag. p. 47,318. ISBN 978-3-13-181544-6.
- ↑ R.E. Banks, B.E. Smart, J.C. Tatlow (2013). Organofluorine Chemistry Principles and Commercial Applications. Springer Science & Business Media. p. 325. ISBN 978-1-4899-1202-2.
- ↑ Maynard B. Chenoweth (2012). Modern Inhalation Anesthetics. Springer Science & Business Media. p. 424. ISBN 978-3-642-65055-0.
- ↑ Ernst W. Alther (2013). Pharmacology of Fluorides. Springer Science & Business Media. p. 538. ISBN 978-3-662-25198-0.
- ↑ Google Patents: US3351671A - Preparation of pentafluoroiodoethane - Google Patents, retrieved 7 January 2019.
- ↑ Alexander Schönberg (2012). Preparative Organic Photochemistry. Springer Science & Business Media. p. 174. ISBN 978-3-642-87918-0.
- ↑ Google Patents: US20080200735A1 - Catalyst for the synthesis of CF3I and CF3CF2I - Google Patents, retrieved 7 January 2019.
 |  |
