Physics:Graphene foam

Schematic of the synthesis of graphene foam using a Ni template (top) and photographs of the products (bottom)

Electron micrographs of the graphene foam prepared using a Ni template

Graphene foam is a solid, open-cell foam made of single-layer sheets of graphene. It is a candidate substrate for the electrode of lithium-ion batteries.

Synthesis

The foam can be manufactured using vapor deposition to coat a metal foam, a three-dimensional mesh of metal filaments. The metal is then removed.

Applications

Electrode

A physically flexible battery was created using the foam for electrodes. The anode was made by coating the foam with a lithium-titanium compound (Li₄Ti₅O₁₂) and the cathode by coating the foam with LiFePO₄. Both electrodes were lightweight and their large surface area provided high energy density of 110 Wh/kg, comparable to commercial batteries.

Power density was much greater than a typical battery. At a rate that completely discharged the material in 18 seconds, power delivered was 80 percent of what it produced during an hour-long discharge. Performance remained stable through 500 charge/discharge cycles.

Support

In 2017 researchers used carbon nanotubes to reinforce a foam. The latter material supports 3,000 times its own weight and can return to its original shape when unweighted. Nanotubes, a powdered nickel catalyst and sugar were mixed. Dried pellets of the substance were then compressed in a steel die in the shape of a screw. The nickel was removed, leaving a screw-shaped piece of foam. The nanotubes' outer layers split and bonded with the graphene.

See also

• Aerographene
• Foam
• Lithium-ion battery

Further reading

• Paronyan, Tereza M.; Thapa, Arjun Kumar; Sherehiy, Andriy; Jasinski, Jacek B.; Jangam, John Samuel Dilip (6 January 2017). "Incommensurate Graphene Foam as a High Capacity Lithium Intercalation Anode". Scientific Reports 7 (1): 39944. doi:10.1038/srep39944. PMID 28059110. Bibcode: 2017NatSR...739944P.