Chemistry:Telluride iodide

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Short description: Class of chemical compounds

The telluride iodides are chemical compounds that contain both telluride ions (Te2−) and iodide ions (I−). They are in the class of mixed anion compounds or chalcogenide halides.[1]

Tellurium does not normally bond with iodine, but can form many different units with bonds to other tellurium atoms.

List

name formula system space group unit cell volume density properties ref
Copper telluride iodide CuTeI tetrahedral I41/amd a = 17.170, c = 4.876, and Z = 16 Cu+1 ion conductor; metallic grey [2][3]
(CuI)3Cu2TeS3 P3121 [1]
gallium telluride iodide GaTeI orthorhombic band gap 2.55 [1]
Ge40.0Te5.3I8 cubic Pm3n a=10.815 Z = 1 1265.0 6.023 band gap 0.8 eV; clathrate [4]
α-Arsenic telluride iodide AsTeI monoclinic P21 a=8.965 b=4.042 c=10.341 β=90.75 Z=4 5.84 melt 281°C black [5]
β-Arsenic telluride iodide AsTeI cubic Fm3m a=5.791 Z=2 5.63 black metallic [5]
As4Te5I2 monoclinic a=14.58 b=4.00 c=12.26 β=95.0 Z=2 5.51 melt 303 °C metallic [5]
triniobium telluride heptaiodide Nb3TeI7 [1]
NbTe4I P21/c a=7.695 b=15.393 c=13.438 β=100.84 Z=8 1563.2 6.205 black metallic [6]
diniobium hexatelluride iodide Nb2Te6I P21/c a=9.197 b=13.387 c=9.651 β=112.36 1093.8 6.548 [1][7]
Nb4Te12I monoclinic C12/c1 a=21.957 b=6.147 c=19.925 β=122.40 Z=4 2270.6 5.8 black [8]
Nb4Te17I4 monoclinic C2/c a = 16.199 b = 8.128 c = 27.355 β = 110.84°, Z = 4 black metallic [9]
Mo3Tel0Il0 [1]
[Mo3Se7(TeI3)I2]I monoclinic P23/n a=10.4969 b=13.029 c=16.567 β =102.921° Z=4 2208.3 5.202 [1][10]
[Mo3Te7(TeI3)3]2(I)(TeI3) triclinic P1 a=11.2148 b=11.6550 c=16.6798 α=92.124 β=102.223 γ=117.427 Z= 1868.4 5.374 [1][10]
Palladium telluride iodide PdTeI a=7.821 c=5.659 brass yellow [11][12]
Ag23Te12I orthorhombic Pnnm honeycomb Te [1]
Ag19Te6Br5.4I1.6 orthorhombic Pnma electric conductor [1]
indium telluride iodide InTeI monoclinic P21/c [13]
Antimony telluride iodide SbTeI triclinic P1 [1]
(Sb2Te2)I[AlI4] monoclinic P21/n [1]
La2TeI2 rhombohedral R3m a = 4.5074 c = 32.528 Z = 3 metallic [1][14]
Er17.3Te24I8 Fd3m a=12.020 [15]
Ta3TeI7 hexagonal P63mc [1]
[TaTe4]4[PtI6]I2 triclinic P1 a=16.831 b=17.740 c=19.018 α=93.57 β=94.08 γ=102.09 Z=1 977.65 [16]
TaTe4I triclinic P1 a=6.679 b=7.787 c=8.581 α=112.76 β=102.60 γ=101.25 Z=2 381.8 7.118 black [6]
W2Cl12Te6I2 [17]
Gold telluride iodide AuITe monoclinic a=7.317 b=7.626 c=7.249 β=106.33 7.73 semiconductor band gap 0.9 grey melt 360°C [18]
Gold telluride diiodide AuITe2 orthorhombic Pmmb a = 4.056 Å, b = 12.579 Å, c = 4.741 Å, Z = 2 241.9 7.989 silvery white conductor melt 440°C [19]
Hg3Te2I2 greyish red [1]
Hg3Te2BrI monoclinic C2 18.376 b=9.587 c=10.575 β=100.11° [20]
Hg3TeI4 cubic F43m a=6.244 Z=(80% partial occupancy) 243.4 7.03 decompose 273°C dark ruby red [21]
Bismuth telluride iodide BiTeI P3m1 / Pnma over 3.9 GPa Weyl semimetal; under semimetal [1]
ThTe2I2 monoclinic C2/m a  = 7.642 b  = 14.336 c  = 7.727 and β = 111.27° Z = 4 [22]
[Ta7(Se2)14][U2I10]2 orthorhombic Cccm a = 21.5134 b = 22.1619 and c = 16.7834 Z=4 [23]

References

  1. ↑ 1.00 1.01 1.02 1.03 1.04 1.05 1.06 1.07 1.08 1.09 1.10 1.11 1.12 1.13 1.14 1.15 Xiao, Jin-Rong; Yang, Si-Han; Feng, Fang; Xue, Huai-Guo; Guo, Sheng-Ping (September 2017). "A review of the structural chemistry and physical properties of metal chalcogenide halides". Coordination Chemistry Reviews 347: 23–47. doi:10.1016/j.ccr.2017.06.010. 
  2. ↑ Carkner, Philip M.; Haendler, Helmut M. (June 1976). "The crystal structure of copper bromide telluride" (in en). Journal of Solid State Chemistry 18 (2): 183–189. doi:10.1016/0022-4596(76)90094-3. Bibcode: 1976JSSCh..18..183C. 
  3. ↑ Fenner, J.; Rabenau, A. (September 1976). "Über Tellurhalogenide des Kupfers mit hoher Ionen-Teilleitfähigkeit Die Kristallstruktur von CuTeJ" (in de). Zeitschrift für anorganische und allgemeine Chemie 426 (1): 7–14. doi:10.1002/zaac.19764260103. ISSN 0044-2313. 
  4. ↑ Kovnir, Kirill A.; Abramchuk, Nikolay S.; Zaikina, Julia V.; Baitinger, Michael; Burkhardt, Ulrich; Schnelle, Walter; Olenev, Andrei V.; Lebedev, Oleg I. et al. (2006-05-01). "Ge 40.0 Te 5.3 I 8 : synthesis, crystal structure, and properties of a new clathrate-I compound" (in en). Zeitschrift für Kristallographie - Crystalline Materials 221 (5–7): 527–532. doi:10.1524/zkri.2006.221.5-7.527. ISSN 2196-7105. Bibcode: 2006ZK....221..527K. https://www.degruyter.com/document/doi/10.1524/zkri.2006.221.5-7.527/html. 
  5. ↑ 5.0 5.1 5.2 Kniep, Rüdiger; Reski, Horst Dieter (February 1981). "Chalcogenide Iodides of Arsenic" (in en). Angewandte Chemie International Edition in English 20 (2): 212–214. doi:10.1002/anie.198102121. ISSN 0570-0833. 
  6. ↑ 6.0 6.1 Tremel, Wolfgang (October 1992). "NbTe4I und TaTe4I, zwei neue Tellurid-Iodide mit Kettenstruktur" (in de). Chemische Berichte 125 (10): 2165–2170. doi:10.1002/cber.19921251002. 
  7. ↑ Tremel, Wolfgang (March 1992). "Niobium telluride iodide, Nb2Te6I, a pseudo-two-dimensional compound with a new mode of transition-metal bonding for a dichalcogen group" (in en). Inorganic Chemistry 31 (5): 755–760. doi:10.1021/ic00031a012. ISSN 0020-1669. 
  8. ↑ Deng, S.; Zhuang, H.; Lu, C.; Huang, Jinshun; Huang, Jingling (1993-06-15). "A new type of one-dimensional compound: structure of Nb4(Te2)4Te4I". Acta Crystallographica Section C Crystal Structure Communications 49 (6): 1135–1137. doi:10.1107/S010827019201285X. Bibcode: 1993AcCrC..49.1135D. http://scripts.iucr.org/cgi-bin/paper?S010827019201285X. 
  9. ↑ Tremel, Wolfgang (January 1994). "Nb4Te17I4, a New Pseudo One-Dimensional Solid-State Polytelluride" (in de). Chemische Berichte 127 (1): 11–14. doi:10.1002/cber.19941270103. 
  10. ↑ 10.0 10.1 Sokolov, Maxim N.; Gushchin, Artem L.; Abramov, Pavel A.; Virovets, Alexander V.; Peresypkina, Eugenia V.; Fedin, Vladimir P. (May 2007). "Synthesis and Structures of Mo 3 Se 7 Te 2 Br 10 , Mo 3 Se 7 TeI 6 , and Mo 6 Te 21 I 22 Containing TeX 3 - (X = Br, I) Ligands Coordinated to a Triangular Cluster Core †" (in en). Inorganic Chemistry 46 (11): 4677–4682. doi:10.1021/ic0700553. ISSN 0020-1669. PMID 17465541. 
  11. ↑ Güler-Kılıç, Sümeyra; Kılıç, Çetin (2015-06-08). "Crystal and electronic structure of BiTeI, AuTeI, and PdTeI compounds: A dispersion-corrected density-functional study" (in en). Physical Review B 91 (24): 245204. doi:10.1103/PhysRevB.91.245204. ISSN 1098-0121. Bibcode: 2015PhRvB..91x5204G. 
  12. ↑ Thiele, Gerhard; Köhler-Degner, Maria; Wittmann, Kurt; Zoubek, Gerd (November 1978). "PdTeI and Pd2SeI3 - The First Chalcogenide Halides of a Platinum Metal" (in en). Angewandte Chemie International Edition in English 17 (11): 852–853. doi:10.1002/anie.197808521. ISSN 0570-0833. 
  13. ↑ Lange, Stefan; Nilges, Tom (May 2006). "Ag10Te4Br2: A New Silver(I) (poly)Chalcogenide Halide Solid Electrolyte". Chemistry of Materials 18 (10): 2538–2544. doi:10.1021/cm060226m. 
  14. ↑ Ryazanov, Mikhail; Simon, Arndt; Mattausch, Hansjürgen (December 2006). "La 2 TeI 2 : A New Layered Telluride Iodide with Unusual Electrical Properties" (in en). Inorganic Chemistry 45 (26): 10728–10733. doi:10.1021/ic061675r. ISSN 0020-1669. PMID 17173429. 
  15. ↑ Stöwe, K (August 1998). "Nonstoichiometry in Er–Te Binary and Er–Te–I Ternary Systems" (in en). Journal of Solid State Chemistry 139 (1): 57–65. doi:10.1006/jssc.1998.7807. 
  16. ↑ Tremel, Wolfgang; Stork, Karl-Ludwig (1993-09-01). "[TaTe4]4[PtI6]I2, ein neues quaternäres Tellurid-Iodid mit Kettenstruktur / [TaTe4]4[PtI6]I2, A New Quaternary Telluride-Iodide with Chain Structure". Zeitschrift für Naturforschung B 48 (9): 1155–1160. doi:10.1515/znb-1993-0901. ISSN 1865-7117. 
  17. ↑ Beck, Johannes (1994-02-01). "New Forms and Functions of Tellurium: From Polycations to Metal Halide Tellurides" (in en). Angewandte Chemie International Edition in English 33 (2): 163–172. doi:10.1002/anie.199401631. ISSN 0570-0833. 
  18. ↑ Rabenau, A.; Rau, H.; Rosenstein, G. (August 1970). "Telluride halides of gold" (in en). Journal of the Less Common Metals 21 (4): 395–401. doi:10.1016/0022-5088(70)90043-3. 
  19. ↑ Haendler, H.M.; Mootz, D.; Rabenau, A.; Rosenstein, G. (June 1974). "The crystal structures of AuTe2Cl and AuTe2I" (in en). Journal of Solid State Chemistry 10 (2): 175–181. doi:10.1016/0022-4596(74)90024-3. Bibcode: 1974JSSCh..10..175H. 
  20. ↑ Minets, Yu.V; Voroshilov, Yu.V; Pan’ko, V.V (March 2004). "The structures of mercury chalcogenhalogenides Hg3X2Hal2" (in en). Journal of Alloys and Compounds 367 (1–2): 109–114. doi:10.1016/j.jallcom.2003.08.020. 
  21. ↑ Wiedemeier, Heribert; Hutchins, Mark A.; Grin, Yuri; Feldmann, Claus; von Schnering, Hans Georg (November 1997). "The Synthesis and Crystal Structure of Hg3TeI4" (in en). Zeitschrift für anorganische und allgemeine Chemie 623 (11): 1843–1846. doi:10.1002/zaac.19976231129. ISSN 0044-2313. 
  22. ↑ Rocker, Frank; Tremel, Wolfgang (2001). "Synthesis and Structure of ThTe2I2" (in en). Zeitschrift für anorganische und allgemeine Chemie 627 (6): 1305–1308. doi:10.1002/1521-3749(200106)627:6<1305::AID-ZAAC1305>3.0.CO;2-J. ISSN 1521-3749. https://onlinelibrary.wiley.com/doi/abs/10.1002/1521-3749%28200106%29627%3A6%3C1305%3A%3AAID-ZAAC1305%3E3.0.CO%3B2-J. 
  23. ↑ Wells, Daniel M.; Ibers, James A. (March 2010). "The [U 2 I 10 ] 2- Anion: Synthesis and Structure of [Ta 7 (Se 2 ) 14 ][U 2 I 10 ] 2" (in en). Zeitschrift für anorganische und allgemeine Chemie 636 (3–4): 440–442. doi:10.1002/zaac.200900416. 
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LiI BeI2 BI3 CI4 NI3 I2O4,
I2O5,
I4O9 		IF,
IF3,
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IF7 		Ne
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P2I4 		S ICl,
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RbI SrI2 YI3 ZrI4 NbI5 Mo Tc Ru Rh Pd AgI CdI2 InI3 SnI4,
SnI2 		SbI3 TeI4 I Xe
CsI BaI2   HfI4 TaI5 W Re Os Ir Pt AuI Hg2I2,
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Fr RaI2   Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
↓
La Ce Pr Nd Pm SmI2 Eu Gd TbI3 Dy Ho Er Tm Yb Lu
Ac ThI4 Pa UI3,
UI4 		Np Pu Am Cm Bk Cf EsI3 Fm Md No Lr



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