Chemistry:Rozen's reagent
From HandWiki
In organic chemistry, Rozen's Reagent or Rozen's epoxidation reagent is a solution of hypofluorous acid and water in acetonitrile.[1][2][3]
The reagent is generated in situ by passing gaseous fluorine through "wet" acetonitrile.[1][4]
References
- ↑ 1.0 1.1 Rozen, Shlomo (2001). "Hypofluorous Acid". Encyclopedia of Reagents for Organic Synthesis. doi:10.1002/047084289X.rh074.
- ↑ Rozen, Shlomo (2014). "HOF·CH3CN: Probably the Best Oxygen Transfer Agent Organic Chemistry Has To Offer". Acc. Chem. Res. 47: 2378–2389. doi:10.1021/ar500107b.
- ↑ Singh, Raman; Kaur, Rajneesh; Gupta, Tarang; Kulbir, Kulbir; Singh, Kuldeep (2019). "Applications of Rozen's Reagent in Oxygen-Transfer and C-H Activation Reactions". Synthesis 51: 371–383. doi:10.1055/s-0037-1609638.
- ↑ Rozen, Shlomo; Bareket, Yifat (1997-03-01). "Oxidation of Sulfur-Containing Compounds with HOF·CH3CN". The Journal of Organic Chemistry 62: 1457–1462. doi:10.1021/jo961862e.
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