Chemistry:Eugenitin
From HandWiki
| |
| Names | |
|---|---|
| IUPAC name
5-Hydroxy-7-methoxy-2,6-dimethylchromen-4-one
| |
| Preferred IUPAC name
5-Hydroxy-7-methoxy-2,6-dimethyl-4H-1-benzopyran-4-one | |
| Identifiers | |
3D model (JSmol)
|
|
| ChemSpider | |
PubChem CID
|
|
| |
| |
| Properties | |
| C12H12O4 | |
| Molar mass | 220.224 g·mol−1 |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
 verify (what is   ?)
| |
| Infobox references | |
Eugenitin is a chromone derivative, a type of phenolic compound found in cloves. It has also been isolated from the fungal species Cylindrocarpon sp. C.M.I. 127996.[1]
Synthesis
Eugenitin has also synthethised using the Kostanecki sodium acetate-acetic anhydride cyclization of C-methylphloracetophenone in 1952[2] and from visnagin, khellin and khellol in 1953.[3]
See also
References
- ↑ Coombe, RG; Lowe, HIC; Watson, TR (1972). "Fungal metabolites. I. Chromone and naphthoquinone metabolites from a Cylindrocarponspecies". Australian Journal of Chemistry 25 (4): 875. doi:10.1071/CH9720875.
- ↑ Whalley, W. B. (1952). "A New Synthesis of Eugenitin". Journal of the American Chemical Society 74 (22): 5795–5796. doi:10.1021/ja01142a530.
- ↑ Schönberg, Alexander; Badran, Nasry; Starkowsky, Nicolas A. (1953). "Furo-chromones and -Coumarins. VII. Degradation of Visnagin, Khellin and Related Substances; Experiments with Chromic Acid and Hydrogen Peroxide; and a Synthesis of Eugenitin". Journal of the American Chemical Society 75 (20): 4992. doi:10.1021/ja01116a032.
 |  |
