Chemistry:Deuterated DMF
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| IUPAC name
1-Deuterio-N,N-bis(trideuteriomethyl)formamide[citation needed]
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Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |||
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| Infobox references | |||
|Section1=! colspan=2 style="background: #f8eaba; text-align: center;" |Identifiers
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| Abbreviations | DMF-d7[citation needed] |-
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| 1908468 |-
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- 224-745-8
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| UN number
| 2265
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- InChI=1S/C3H7NO/c1-4(2)3-5/h3H,1-2H3/i1D3,2D3,3DKey: ZMXDDKWLCZADIW-YYWVXINBSA-N
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- [2H]C(=O)N(C([2H])([2H])[2H])C([2H])([2H])[2H]
|- |Section2=! colspan=2 style="background: #f8eaba; text-align: center;" |Properties
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| C32H7NO
|- | Molar mass
| 80.1369 g mol−1
|- | Appearance | Colourless liquid |-
| Density | 1.03 g mL−1 |-
| Boiling point | 153 °C (307 °F; 426 K)
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| 1.428 |- |Section3=! colspan=2 style="background: #f8eaba; text-align: center;" |Hazards
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| GHS pictograms
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| GHS Signal word
|DANGER
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| H312, H319, H332, H360 |-
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| P280, P305+351+338, P308+313 |-
| Flash point
| 58 °C (136 °F; 331 K)
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| Explosive limits | 2.2–15.2% |-
| colspan=2 style="text-align:left; background-color:#f1f1f1;" | Lethal dose or concentration (LD, LC): |-
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- 2.8 g kg−1 (oral, rat)
- 1.5–4.72 g kg−1 (dermal, rabbit)
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|- |Section4=! colspan=2 style="background: #f8eaba; text-align: center;" |Related compounds
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|- }} Deuterated dimethylformamide ((CD3)2NCOD), also known as deuterated DMF, is an isotopologue of DMF ((CH3)2NCOH) in which the hydrogen atom ("H") is replaced with a deuterium isotope ("D"). Deuterated DMF is a relatively uncommon solvent used in NMR spectroscopy.[1][2]
References
- ↑ Walker, Lynn M.; Wagner, Norman J. (1996-01-01). "SANS Analysis of the Molecular Order in Poly(γ-benzyl l -glutamate)/Deuterated Dimethylformamide (PBLG/d-DMF) under Shear and during Relaxation" (in en). Macromolecules 29 (6): 2298–2301. doi:10.1021/ma951127p. ISSN 0024-9297. https://pubs.acs.org/doi/10.1021/ma951127p.
- ↑ Kim, Ahran; Kim, Cheal (2019-05-14). "A hydrazono-quinoline-based chemosensor sensing In3+ and Zn2+via fluorescence turn-on and ClO−via color change in aqueous solution" (in en). New Journal of Chemistry 43 (19): 7320–7328. doi:10.1039/C9NJ00899C. ISSN 1369-9261. https://pubs.rsc.org/en/content/articlelanding/2019/nj/c9nj00899c.
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