Chemistry:Arsenide chloride

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Arsenide chlorides or chloride arsenides are compounds containing anions composed of chloride (Cl−) and arsenide (As3−). They can be considered as mixed anion compounds. They are in the category of pnictidehalides. Related compounds include the arsenide bromides, arsenide iodides, phosphide chlorides, and antimonide chlorides.

List

formula system space group unit cell Å volume density comment ref
Ca3AsCl3 Pm3m a= 5.760 [1]
Sr2AsCl dark violet [2]
Cd8As7Cl cubic P23 a=7.266, Z=1 [3]
Hg7.4As4Cl6 cubic Pa3 a= 12.178, Z= 4 [4]
(Hg6As4)(HgCl6)Hg0.5 cubic Pa3 a=12.189 Z=4 1810.7 7.398 yellow; air stable; band gap 2.01 [5]
(Hg6As4)[TiCl6]Cl cubic Pa3 a = 1209.4 [6]
[Hg4As2][ZrCl6] orthorhombic Pbca a=13.277 b=13.420 c=16.814 Z=8 2769.1 5.570 dark yellow [7]
[Hg4As2][HfCl6] orthorhombic Pbca a=13.273 b=13.413 c=16.809 Z=8 2992 5.964 orange [7]
(Hg3AsS)(GaCl4) hexagonal P63/mc a =7.245, c =11.960 , Z = 2 543.6 5.622 light yellow [8]
Hg3AsS4Cl hexagonal P63mc a = 7.431, c = 9.003 Z=2 yellow; air stable [9]
[Hg6As4](CuCl3)2 monoclinic I2/a a = 14.690, b = 9.1851, c = 20.285, β=92.170, Z=6 [10]
(Hg9.75As5.5)(GaCl4)3 orthorhombic Pmn21 a=22.567 b=12.146 c=12.983 Z=4 3559 5.604 [11]
(Hg6As4)[MoCl6]Cl cubic Pa3 a = 12.078 [6]
[Hg6As4](AgCl3)2 monoclinic I2/a a = 14.690, b = 9.1851, c = 20.285, β = 93.17°, Z = 4 [10][12]
(Hg6As4)(CdCl6)Hg0.5 cubic Pa3 a=12.172 Z=4 1803.2 7.104 yellow; air stable; band gap 2.05 [5]
[Hg6As4](InCl6)Cl cubic Pa3 a = 12.109, Z = 4 dark red [13]
[Hg6As4Cl3](SnCl3)Hg0.13 cubic P213 a=12.233 Z=4 [14]
Hg3As2TlCl3 orthorhombic Pbcm a = 6.292, b = 12.341 c = 12.248 Z=4 red [15]
Hg6As4BiCl7 cubic Pa3 a=12.178 Z=4 [16]
[Hg4As2][UCl6] orthorhombic Pbca a=13.316 b=13.636 c=16.853 Z=8 3060.0 6.090 red [7][17]

References

  1. ↑ Hadenfeldt, C.; Vollert, H. O. (August 1982). "Darstellung, thermisches Verhalten und Kristallstruktur des Calciumarsenidchlorids Ca3AsCl3" (in de). Zeitschrift für anorganische und allgemeine Chemie 491 (1): 113–118. doi:10.1002/zaac.19824910115. ISSN 0044-2313. https://onlinelibrary.wiley.com/doi/10.1002/zaac.19824910115. 
  2. ↑ Hadenfeldt, Claus (1976-04-01). "Darstellung und Eigenschaften von Ca 2 AsBr, Sr 2 AsCl und Ca 3 AsBr 3 .: Preparation and Properties of Ca 2 AsBr, Sr 2 AsCl, and Ca 3 AsBr 3" (in en). Zeitschrift für Naturforschung B 31 (4): 408–410. doi:10.1515/znb-1976-0403. ISSN 1865-7117. 
  3. ↑ Shevelkov, Andrei V.; Reshetova, Ludmila N.; Popovkin, Boris A. (December 1997). "Cd8As7Cl: A Novel Pnictidohalide with a New Structure Type" (in en). Journal of Solid State Chemistry 134 (2): 282–285. doi:10.1006/jssc.1997.7555. Bibcode: 1997JSSCh.134..282S. https://linkinghub.elsevier.com/retrieve/pii/S0022459697975551. 
  4. ↑ Shevelkov, Andrei V.; Dikarev, Evgeny V.; Popovkin, Boris A. (November 1996). "Two New Cubic Structures of Mercury Arsenidehalides" (in en). Journal of Solid State Chemistry 126 (2): 324–327. doi:10.1006/jssc.1996.0344. Bibcode: 1996JSSCh.126..324S. https://linkinghub.elsevier.com/retrieve/pii/S0022459696903448. 
  5. ↑ 5.0 5.1 Zou, Jian-Ping; Li, Yan; Fu, Ming-Lai; Guo, Guo-Cong; Xu, Gang; Liu, Xue-Hui; Zhou, Wei-Wei; Huang, Jin-Shun (March 2007). "The Synthesis, Crystal and Band Structures, and Properties of the Quaternary Supramolecular Complexes [Hg 6 Z 4 (MX 6 )Hg y (Z = As, Sb; M = Hg, Cd; X = Cl, Br, I; y = 0, 0.5, 0.6)"] (in en). European Journal of Inorganic Chemistry 2007 (7): 977–984. doi:10.1002/ejic.200600894. ISSN 1434-1948. https://onlinelibrary.wiley.com/doi/10.1002/ejic.200600894. 
  6. ↑ 6.0 6.1 Beck, Johannes; Neisel, Udo (2000). "Synthese, Kristallstrukturen und Magnetismus von (Hg6As4)[MoCl6]Cl, (Hg6As4)[TiCl6]Cl und (Hg6As4)[TiBr6]Br". Zeitschrift für Anorganische und Allgemeine Chemie 626 (7): 1620–1626. doi:10.1002/1521-3749(200007)626:7<1620::AID-ZAAC1620>3.0.CO;2-R. 
  7. ↑ 7.0 7.1 7.2 Li, Xiao-Guo; Jiang, Xiao-Ming; Zhang, Ming-Jian; Liu, Bin-Wen; Fan, Yu-Hang; Guo, Guo-Cong; Huang, Jin-Shun (2013-12-02). "Three-Dimensional Mercury Pnictide [Hg 4 Z 2 ] 2+ Cationic Frameworks Stabilized by Tetravalent Metal Halide Anions in Supramolecular Complexes: [Hg 4 Z 2 ][MCl 6 ] (Z = P, As; M = Zr, Hf)" (in en). European Journal of Inorganic Chemistry 2013 (35): 5980–5986. doi:10.1002/ejic.201300888. ISSN 1434-1948. 
  8. ↑ Jiang, Xiao-Ming; Li, Xiao-Guo; Fan, Yu-Hang; Liu, Bin-Wen; Zeng, Hui-Yi; Guo, Guo-Cong (2013). "New mercury-contained cationic frameworks stabilized by (GaCl4)− unit via weak electrostatic forces in supramolecular compounds (Hg11P4)(GaCl4)4 and (Hg3AsS)(GaCl4)" (in en). Dalton Transactions 42 (43): 15475–15481. doi:10.1039/c3dt51451j. ISSN 1477-9226. PMID 24022795. http://xlink.rsc.org/?DOI=c3dt51451j. 
  9. ↑ Beck, Johannes; Hedderich, Sylvia; Köllisch, Klaus (2000-12-01). "Hg 3 AsE 4 X (E = S, Se; X = Cl, Br, I), a Family of Isotypic Compounds with an Acentric, Layered Structure" (in en). Inorganic Chemistry 39 (25): 5847–5850. doi:10.1021/ic0003527. ISSN 0020-1669. PMID 11151388. https://pubs.acs.org/doi/10.1021/ic0003527. 
  10. ↑ 10.0 10.1 Oleneva, Olga S.; Olenev, Andrei V.; Dikarev, Evgeny V.; Shevelkov, Andrei V. (June 2005). "Solid State Supramolecular Complexes [Hg6As4(CuX3)2 (X = Cl, Br): One-Dimensional Helical Guest in a Three-Dimensional Host Framework"] (in en). Journal of Cluster Science 16 (2): 273–285. doi:10.1007/s10876-005-4548-y. ISSN 1040-7278. http://link.springer.com/10.1007/s10876-005-4548-y. 
  11. ↑ Jiang, Xiao-Ming; Yan, Zhi-Bo; Liu, Dan; Wang, Ke-Feng; Guo, Guo-Cong; Li, Shao-Zhen; Liu, Jun-Ming (October 2014). "Large and Fast Single-Crystal Resistive Humidity Sensitivity of Metal Pnictide Halides Containing van der Waals Host-Guest Interactions" (in en). Chemistry: An Asian Journal 9 (10): 2872–2879. doi:10.1002/asia.201402572. PMID 25110860. 
  12. ↑ Oleneva, Olga S.; Olenev, Andrei V.; Dikarev, Evgeny V.; Shevelkov, Andrei V. (October 2004). "From Discrete to Extended Guests: A Novel Supramolecular [Hg 6 As 4 (AgCl 3 ) 2 Assembly Featuring One-Dimensional (AgCl 3 ) 2− Anions"] (in en). European Journal of Inorganic Chemistry 2004 (20): 4006–4010. doi:10.1002/ejic.200400205. ISSN 1434-1948. https://onlinelibrary.wiley.com/doi/10.1002/ejic.200400205. 
  13. ↑ Olenev, A. V.; Baranov, A. I.; Shatruk, M. M.; Tyablikov, A. S.; Shevelkov, A. V. (2002). "Synthesis and the crystal structure of [Hg6As4(InCl6)Cl: influence of covalent and electrostatic factors on the supramolecular structure"]. Russian Chemical Bulletin 51 (3): 444–448. doi:10.1023/A:1015500116907. http://link.springer.com/10.1023/A:1015500116907. 
  14. ↑ Olenev, Andrei V.; Baranov, Alexei I.; Shevelkov, Andrei V.; Popovkin, Boris A. (2002). "A New Family of Supramolecular Complexes with 3D Cationic Hg/Z Frameworks, SnX3− Guest Anions (Z = P, as, Sb; X = Cl, Br, I): Crystal Structures and Host−Guest Interactions". European Journal of Inorganic Chemistry 2002 (3): 547–553. doi:10.1002/1099-0682(200203)2002:3<547::AID-EJIC547>3.0.CO;2-N. 
  15. ↑ Beck, Johannes; Neisel, Udo (2001). "Polykationische Hg-Pnictid-Gerüste mit einer neuen Füllungsvariante in den Strukturen von Hg3As2TlCl3 und Hg3Sb2TlBr3". Zeitschrift für Anorganische und Allgemeine Chemie 627 (8): 2016–2022. doi:10.1002/1521-3749(200108)627:8<2016::AID-ZAAC2016>3.0.CO;2-N. 
  16. ↑ Beck, Johannes; Hedderich, Sylvia; Neisel, Udo (November 2000). "Synthesis and Crystal Structures of Hg6Sb5Br7, Hg6As4BiCl7, and Hg6Sb4BiBr7, Built of a Polycationic Mercury-Pnictide Framework with Trapped Anions" (in en). Journal of Solid State Chemistry 154 (2): 350–355. doi:10.1006/jssc.2000.8794. Bibcode: 2000JSSCh.154..350B. https://linkinghub.elsevier.com/retrieve/pii/S0022459600987942. 
  17. ↑ Bugaris, Daniel E.; Ibers, James A. (December 2008). "Syntheses, structures, and magnetic and optical properties of the compounds [Hg3Te2[UCl6] and [Hg4As2][UCl6]"] (in en). Journal of Solid State Chemistry 181 (12): 3189–3193. doi:10.1016/j.jssc.2008.08.019. Bibcode: 2008JSSCh.181.3189B. https://linkinghub.elsevier.com/retrieve/pii/S0022459608004465. 



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