Chemistry:2-Aminobiphenyl
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| Preferred IUPAC name
[1,1′-Biphenyl]-2-amine | |
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| Properties | |
| C12H11N | |
| Molar mass | 169.227 g·mol−1 |
| Appearance | white solid |
| Density | 1.077 g/cm3 |
| Melting point | 51 °C (124 °F; 324 K) |
| Boiling point | 299 °C (570 °F; 572 K) |
| Hazards | |
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| GHS Signal word | Warning |
| H302, H351, H412 | |
| P201, P202, P264, P270, P273, P281, P301+312, P308+313, P330, P405, P501 | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
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2-Aminobiphenyl (2-ABP) is an organic compound with the formula C6H5C6H4NH2. It is an amine derivative of biphenyl. It is a colorless solid, although aged samples can appear colored even black.[1] Palladacycles obtained from 2-aminobiphenyl are popular catalysts for cross-coupling.[2]
It is prepared by hydrogenation of 2-nitrobiphenyl.[3]
See also
References
- ↑ M. J. S. Dewar; R. B. K. Dewar; Z. L. F. Gaibel (1966). "10-Methyl-10,9-borazarophenanthrene". Org. Synth. 46: 65. doi:10.15227/orgsyn.046.0065.
- ↑ Bruneau, A.; Roche, M.; Alami, M.; Messaoudi, S. (2015). "2-Aminobiphenyl Palladacycles: The "Most Powerful" Precatalysts in C–C and C–Heteroatom Cross-Couplings". ACS Catalysis 5 (2): 1386-1396. doi:10.1021/cs502011x.
- ↑ G. David Mendenhall; Peter A. S. Smith (1966). "2-Nitrocarbazole". Org. Synth. 46: 85. doi:10.15227/orgsyn.046.0085.
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