Chemistry:1,5-Dithiacyclooctane
From HandWiki
| |
| Names | |
|---|---|
| Preferred IUPAC name
1,5-Dithiocane | |
| Other names
DTO
| |
| Identifiers | |
3D model (JSmol)
|
|
| ChemSpider | |
PubChem CID
|
|
| |
| |
| Properties | |
| C6H12S2 | |
| Molar mass | 148.28 g·mol−1 |
| Appearance | colorless liquid |
| Melting point | −15 °C (5 °F; 258 K) |
| Boiling point | 245–6 °C (473–43 °F; 518–279 K) |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| Infobox references | |
Tracking categories (test):
1,5-Dithiacyclooctane (DTCO) is an organosulfur compound with the formula (CH2CH2)CH2S)2. This cyclic dithioether is a colorless oil that is soluble in polar solvents. It forms a variety of transition metal thioether complexes.
DTO can be oxidized to the bicyclic dication.[1]
PdCl2_(VIVXUT).png)
DTCO was first prepared in 4% yield by dialkylation of 1,3-propanedithiol with 1,3-dibromopropane.[2]
References
- ↑ Musker, W. Kenneth (1992). "Coordination Chemistry of Bidentate Medium Ring Ligands (Mesocycles)". Coordination Chemistry Reviews 117: 133–57. doi:10.1016/0010-8545(92)80022-J.
- ↑ Meadow, J. R.; Reid, E. E. (1934). "Ring compounds and polymers from polymethylene dihalides and dimercaptans". J. Am. Chem. Soc. 56 (10): 2177–2180. doi:10.1021/ja01325a058.
 |  |
