Biology:Isoeugenol synthase
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Short description: Class of enzymes
| Isoeugenol synthase | |||||||||
|---|---|---|---|---|---|---|---|---|---|
| Identifiers | |||||||||
| EC number | 1.1.1.319 | ||||||||
| Databases | |||||||||
| IntEnz | IntEnz view | ||||||||
| BRENDA | BRENDA entry | ||||||||
| ExPASy | NiceZyme view | ||||||||
| KEGG | KEGG entry | ||||||||
| MetaCyc | metabolic pathway | ||||||||
| PRIAM | profile | ||||||||
| PDB structures | RCSB PDB PDBe PDBsum | ||||||||
| |||||||||
Isoeugenol synthase (EC 1.1.1.319, IGS1, t-anol/isoeugenol synthase 1) is an enzyme with systematic name eugenol:NADP+ oxidoreductase (coniferyl acetate reducing).[1][2][3] This enzyme catalyses the following chemical reaction.[4]
- isoeugenol + acetate + NADP+ [math]\displaystyle{ \rightleftharpoons }[/math] coniferyl acetate + NADPH + H+
The enzyme acts in the reverse direction.
Dexter et al., 2007 finds that the substrate is coniferyl acetate.[5]
References
- ↑ "Eugenol and isoeugenol, characteristic aromatic constituents of spices, are biosynthesized via reduction of a coniferyl alcohol ester". Proceedings of the National Academy of Sciences of the United States of America 103 (26): 10128–33. June 2006. doi:10.1073/pnas.0603732103. PMID 16782809.
- ↑ "The multiple phenylpropene synthases in both Clarkia breweri and Petunia hybrida represent two distinct protein lineages". The Plant Journal 54 (3): 362–74. May 2008. doi:10.1111/j.1365-313X.2008.03412.x. PMID 18208524.
- ↑ "Biosynthesis of t-anethole in anise: characterization of t-anol/isoeugenol synthase and an O-methyltransferase specific for a C7-C8 propenyl side chain". Plant Physiology 149 (1): 384–94. January 2009. doi:10.1104/pp.108.128066. PMID 18987218.
- ↑ "Eugenol synthase genes in floral scent variation in Gymnadenia species". Functional & Integrative Genomics 14 (4): 779–88. December 2014. doi:10.1007/s10142-014-0397-9. PMID 25239559. https://www.zora.uzh.ch/id/eprint/104915/8/ZORA_NL_104915.pdf.
- ↑
- Vogt, Thomas (2010). "Phenylpropanoid Biosynthesis". Molecular Plant 3 (1): 2–20. doi:10.1093/mp/ssp106. PMID 20035037.
- This review cites this research.
- Dexter, Richard; Qualley, Anthony; Kish, Christine M.; Ma, Choong Je; Koeduka, Takao; Nagegowda, Dinesh A.; Dudareva, Natalia; Pichersky, Eran et al. (2006-12-07). "Characterization of a petunia acetyltransferase involved in the biosynthesis of the floral volatile isoeugenol". The Plant Journal 49 (2): 265–275. doi:10.1111/j.1365-313x.2006.02954.x. PMID 17241449.
External links
- Isoeugenol+synthase at the US National Library of Medicine Medical Subject Headings (MeSH)
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